Clusters in sedimentation equilibrium for an experimental hard-sphere-plus-dipolar Brownian colloidal system

Brownian Dynamics Simulations on Hard-Sphere Colloidal Suspensions

Nearly logarithmic decay in the colloidal hard-sphere system.

Nearly logarithmic decay is identified in the data for the mean-squared displacement of the colloidal hard-sphere system at the liquid-glass transition [W. van Megen, Phys. Rev. E 58, 6073 (1998)]. The solutions of the mode-coupling theory for the microscopic equations of motion fit the experimental data well. Based on these equations, the nearly logarithmic decay is explained as the equivalent...

Experimental observation of the crystallization of hard-sphere colloidal particles by sedimentation onto flat and patterned surfaces.

We present a confocal microscopy study of 1.55 microm monodisperse silica hard spheres as they sediment and crystallize at the bottom wall of a container. If the particles sediment onto a feature less flat wall, the two bottom layers crystallize simultaneously and layerwise growth follows. If the wall is replaced by a hexagonal template, only layerwise growth occurs. Our results complement earl...

The Chiral Dipolar Hard Sphere Model

A simple molecular model of chiral molecules is presented in this paper : the chiral dipolar hard sphere model. The discriminatory interaction between enantiomers is represented by electrostatic (or magnetic) dipoles-dipoles interactions : short ranged steric repulsion are represented by hard sphere potential and, in each molecule, two point dipoles are located inside the sphere. The model is d...

Equilibrium glassy phase in a polydisperse hard-sphere system.

The phase diagram of a polydisperse hard-sphere system is examined by numerical minimization of a discretized form of the Ramakrishnan-Yussouff free-energy functional. Crystalline and glassy local minima of the free energy are located and the phase diagram in the density-polydispersity plane is mapped out by comparing the free energies of different local minima. The crystalline phase disappears...